Further studies on vinamidinium salt amine exchange reactions, borohydride reductions and subsequent transformations.

نویسندگان

  • John T Gupton
  • Nakul Telang
  • Xin Jia
  • Benjamin C Giglio
  • James E Eaton
  • Peter J Barelli
  • Mona Hovaizi
  • Kayleigh E Hall
  • R Scott Welden
  • Matthew J Keough
  • Eric F Worrall
  • Kara L Finzel
  • Emily J Kluball
  • Rene P F Kanters
  • Timothy M Smith
  • Stanton Q Smith
  • Shane R Nunes
  • Mathew T Wright
  • Jennifer M Birnstihl
چکیده

Studies directed at the amine exchange reaction of vinamidinium salts followed by sodium borohydride reduction to secondary and tertiary allylic amines are described. The tertiary allylic amines were alkylated and subjected to base mediated rearrangement to yield a variety of highly functionalized tertiary homoallylic amines.

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عنوان ژورنال:
  • Tetrahedron

دوره 66 44  شماره 

صفحات  -

تاریخ انتشار 2010